A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement ( Vol-3,Issue-2,March - April 2018 )
Author: Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan
Keyword: Heavy metal ion, Lab chip sensor, Square-wave anodic stripping voltammetry, in situ measurement.
Abstract: SEM images and FTIR data of the working electrode surface showed that Mn+ ions were adsorbed on chitosan (Chit) and crosslinked chitosan-carbon nanotube (Chit-CNT) films. XPS revealed that chelation of Mn+ ions with the –NH2/–OH groups from chitosan, –COOH group from carbon nanotubes, and aqua ligands represents a possible structure of the active Mn+ species in the Chit-based film. The electrochemical behaviors of the Chit-based film modified screen-printed carbon electrode (SPCE) were characterized for individual and simultaneous detection of Cu2+, Pb2+, Hg2+, Zn2+, Cd2+, and As3+ ions. For individual detection, the concentration range was 0.50–3.00 ppm with a detection limit of 0.4 ppm for Cu2+; 1.0–4.0 ppm with a detection limit of 0.5 ppm for Pb2+; 1.0–5.0 ppm with a detection limit of 0.8 ppm for Hg2+. For simultaneous detection, the lab chip sensor was successfully used to determine the concentrations of Pb2+, Cu2+, Hg2+, and As3+ ions simultaneously.
 P. Huang, M. Cao, Q. Liu, Adsorption of chitosan on chalcopyrite and galena from aqueous suspensions, Colloids and Surfaces A: Physicochem. Eng. Aspects 409 (2012) 167–175.
 J.L. Wang, C. Chen, Chitosan-based biosorbents: Modification and application for biosorption of heavy metals and radionuclides, Bioresour. Technol. 160 (2014) 129–141.
 F.C. Vicentini, T.A. Silva, A. Pellatieri, B.C. Janegitz, O. Fatibello-Filho, R.C. Faria, Pb(II) determination in natural water using a carbon nanotubes paste electrode modified with crosslinked chitosan, Microchem. J. 116 (2014) 191–196.
 M. Ghalkhani, S. Shahrokhian, Adsorptive stripping differential pulse voltammetric determination of mebendazole at a graphene nanosheets and carbon nanospheres/chitosan modified glassy carbon electrode, Sens. Actuators B 185 (2013) 669–674.
 K.Z. Elwakeel, A.A. Atia, E. Guibal, Fast removal of uranium from aqueous solutions using tetraethylenepentamine modified magnetic chitosan resin, Bioresour. Technol. 160 (2014) 107–114.
 V.I. Paz Zaninia, R.E. Giménez, O.E. Linarez Pérez, B.A. López de Mishima, C.D. Borsarelli, Enhancement of amperometric response to tryptophan by proton relay effect of chitosan adsorbed on glassy carbon electrode, Sens. Actuators B 209 (2015) 391–398.
 X. Luo, J. Zeng, S.L. Liu, L.N. Zhang, An effective and recyclable adsorbent for the removal of heavy metal ions from aqueous system: Magnetic chitosan/cellulose microspheres, Bioresour. Technol. 194 (2015) 403–406.
 V.S. Tran, H.H. Ngo, W.S. Guo, J. Zhang, S. Liang, C. Ton-That, X.B. Zhang, Typical low cost biosorbents for adsorptive removal of specific organic pollutants from water, Bioresour. Technol. 182 (2015) 353–363.
 X.Y. Yu, T. Luo, Y.X. Zhang, Y. Jia, B.J. Zhu, X.C. Fu, J.H. Liu, X.J. Huang, Adsorption of lead(II) on O2-plasma-oxidized multiwalled carbon nanotubes: thermodynamics, kinetics, and desorption, ACS Appl. Mater. Interfaces 3 (2011) 2585–2593.
 M.P.N. Bui, C.A. Li, K.N. Han, X.H. Pham, G.H. Seong, Electrochemical determination of cadmium and lead on pristine single-walled carbon nanotube electrodes, Anal. Sci. 28 (2012) 699–704.
 S. Sadeghi, A. Garmroodi, A highly sensitive and selective electrochemical sensor for determination of Cr(VI) in the presence of Cr(III) using modified multi-walled carbon nanotubes/quercetin screen-printed electrode, Mater. Sci. Eng. C 33 (2013) 4972–4977.
 R. Das, S.B. Abd Hamid, M.E. Ali, A.F. Ismail, Multifunctional carbon nanotubes in water treatment: The present, past and future, Desalination 354 (2014) 160–179.
 S.K. Annamalai, B. Palani, K.C. Pillai, Highly stable and redox active nano copper species stabilized functionalized-multiwalled carbon nanotube/chitosan modified electrode for efficient hydrogen peroxide detection, Colloids Surf. A 395 (2012) 207–216.
 Y.G. Wang, L. Shi, L. Gao, Q. Wei, L.M. Cui, L.H. Hu, L.G. Yan, B. Du, The removal of lead ions from aqueous solution by using magnetic hydroxypropyl chitosan/oxidized multiwalled carbon nanotubes composites, J. Colloid Interface Sci. 451 (2015) 7–14.
 C. Jung, J.Y. Heo, J.H. Han, N.G. Her, S.J. Lee, J. Oh, J. Ryu, Y. Yoon, Hexavalent chromium removal by various adsorbents: Powdered activated carbon, chitosan, and single/multi-walled carbon nanotubes, Sep. Purif. Technol. 106 (2013) 63–71.
 Z. Zou, A. Jang, E. MacKnight, P.M. Wu, J. Do, P.L. Bishop, C.H. Ahn, Environmentally friendly disposable sensors with microfabricated on-chip planar bismuth electrode for in situ heavy metal ions measurement, Sens. Actuators B 134 (2008) 18–24.
 A. Bobrowski, A. Królicka, M. Maczuga, J. Zarębski, A novel screen-printed electrode modified with lead film foradsorptive stripping voltammetric determination of cobalt and nickel, Sens. Actuators B 191 (2014) 291– 297.
 T. Ndlovu, B.B. Mamba, S. Sampath, R.W. Krause, O.A. Arotib, Voltammetric detection of arsenic on a bismuth modified exfoliated graphite electrode, Electrochim. Acta 128 (2014) 48–53.
 L. Cui, J. Wu, H.X. Ju, Electrochemical sensing of heavy metal ions with inorganic, organic and bio-materials, Bioresour. Technol. 63 (2015) 276–286.
 W.S. Jung, A. Jang, P.L. Bishop, C.H. Ahn, A polymer lab chip sensor with microfabricated planar silver electrode for continuous and on-site heavy metal measurement, Sens. Actuators B 155 (2011) 145–153.
 G.G. Oliveira, D.C. Azzi, F.C. Vicentini, E.R. Sartori, O. Fatibello-Filho, Voltammetric determination of verapamil and propranolol using a glassy carbon electrode modified with functionalized multiwalled carbon nanotubes within a poly (allylamine hydrochloride) film, J. Electroanal. Chem. 708 (2013) 73–79.
 L. Chen, Z. Li, Y. Meng, P. Zhang, Z.H. Su, Y. Liu, Y. Huang, Y. Zhou, Q.G. Xie, S.Z. Yao, Sensitive square wave anodic stripping voltammetric determination of Cd2+ and Pb2+ ions at Bi/Nafion/overoxidized 2-mercaptoethanesulfonate-tethered polypyrrole/glassy carbon electrode, Sens. Actuators B 191 (2014) 94–101.
 J.R. Rangel-Mendez, R. Monroy-Zepeda, E. Leyva-Ramos, P.E. Diaz-Flores, K. Shirai, Chitosan selectivity for removing cadmium (II), copper (II), and lead (II) from aqueous phase: pH and organic matter effect, J. Hazard. Mater. 162 (2009) 503–511.
 J. Li, B. Renbi, Mechanisms of lead adsorption on Chitosan/PVA hydrogel beads, Langmuir 18 (2002) 9765–9770.
 S.M. Seck, S.Charvet, M. Fall, E. Baudrin, M. Lejeune, M. Benlahsen, Detection of cadmium and copper cations using amorphous nitrogenated carbon thin film electrodes, Electroanalysis 24 (2012) 1839–1846.
 A. Afkhami, H. Bagheri, H. Khoshsafar, M. Saber-Tehrani, M. Tabatabaee, A. Shirzadmehr, Simultaneous trace-levels determination of Hg(II) and Pb(II) ions in various samples using a modified carbon paste electrode based on multi-walled carbon nanotubes and a new synthesized Schiff base, Anal. Chim. Acta 746 (2012) 98–106.
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