Interaction of Metallic Iron with Solutions Containing Humic Acids and Cu(II) ( Vol-2,Issue-6,November - December 2017 )
Author: Rima Binkienė, Ona Gylienė, Romas Ragauskas, Valentinas Gerasimovas
Keyword: Humic acids; Copper ions, Metallic iron; Decontamination.
Abstract: Humic acids are responsible for the heavy metal movement in the environment. In order to diminish soil pollution with heavy metals the treatment of groundwater with metallic iron has been proposed. Investigations with model solutions containing humic acids and Cu(II) have shown that metallic iron is an effective decontaminant for humic acids containing solutions. The application of the mechanical brush-up of the passive layers from surface using rotating systems loaded with iron pieces gives satisfactory results. The decontamination rate depends mainly on solution pH and the iron surface renewal rate. The presence of Cu(II) ions in the solution or metallic copper in the load increase the decontamination rate.
 R. BouKheir, B. Shomar, M.B. Greve, M.H. Greve, On the quantitative relationships between environmental parameters and heavy metals pollution in Mediterranean soils using GIS regression-trees: The case study of Lebanon. Environmental Pollution 206 (2015) 227-235.
 J. Burlakovs, M. Klavins, L. Osinska, O. Purmalis, The Impact of Humic Substances as Remediation Agents to the Speciation Forms of Metals in Soil. APCBEE Procedia 5 ( 2013 ) 192 – 196.
 Wang-Wang Tang, Guang-Ming Zeng, Ji-Lai Gong, Jie Liang, Piao Xu, Chang Zhang, Bin-Bin Huang, Impact of humic/fulvic acid on the removal of heavy metals from aqueous solutions using nanomaterials: A review, Science of the Total Environment 468–469 (2014) 1014–1027.
 Medhat A. Shaker, Hassan M. Albishri, Dynamics and thermodynamics of toxic metals adsorption onto soil-extracted humic acid, Chemosphere 111 (2014) 587–595.
 Qi Wang, ZhiyiXie, Fangbai Li, Using ensemble models to identify and apportion heavy metal pollution sources in agricultural soils on a local scale, Environmental Pollution 206 (2015) 227-235.
 Kai Fang, Dongxing Yuan, Lei Zhang, Lifeng Feng, Yaojin Chen, Yuzhou Wang, Effect of environmental factors on the complexation of iron and humic acid, Journal of Environmental Sciences 27 (2015) 188-196.
 C. Colombo, G. Palumbo, V. Michele Sellitto, H. Goo Cho, C. Amalfitano, P.a Adamo, Stability of coprecipitated natural humic acid and ferrous iron under oxidative conditions, Journal of Geochemical Exploration 151 (2015) 50–56.
 Y. Han, W. Yan, Bimetallic nickel-iron nanoparticles for groundwater decontamination: Effect of groundwater constituents on surface deactivation. Water Res. 66 (2014) 149-159.
 J. Kumpiene, S. Ore, G. Renella, M. Mench, A. Lagerkvist, Ch. Maurice, Assessment of zerovalent iron for stabilization of chromium, copper, and arsenic in soil, Environmental Pollution 144 (2006) 62-69
 J. Kumpiene , I. Castillo Montesinos, A. Lagerkvist, Ch. Maurice, Evaluation of the critical factors controlling stability of chromium, copper, arsenic and zinc in iron-treated soil, Chemosphere 67 (2007) 410–417
 O. Gyliene, T. Vengris, O. Nivinskiene, R. Binkiene, Decontamination of solutions containing Cu(II) and ligands tartrate, glycine and quadrol using metallic iron. J. Hazard. Mater. 175 (2010) 452–459.
 C. Noubactep, ‘A critical review on the process of contaminant removal in Fe0-H2O systems’, Environ. Technol., , 29(2008) 909-920.
 R. Rangsivek, M.R. Jekel, ‘Removal of dissolved metals by zero-valent iron (ZVI):Kinetics, equilibria, processes and implications for stormwater runoff treatment, Water Res.39 (2005) 4153–4163.
 D. Karabelli, C. Uzum, T. Shahwan, A. E. Eroglu, T. B. Scott, K. R. Hallam, I. Lieberwirth, Batch Removal of Aqueous Cu2+ Ions Using Nanoparticles of Zero-Valent Iron: A Study of the Capacity and Mechanism of Uptake, ,Ind. Eng. Chem. Res. 47 (2008) 4758–4764.
 Tingyi Liu, Zhong-Liang Wang, Yanqiu Sun. Manipulating the morphology of nanoscale zero-valent iron on pumice for removal of heavy metals from wastewater, Chemical Engineering Journal 263 (2015) 55–61
 Seol Ah Kim, Seralathan Kamala-Kannan, Kui-Jae Lee, Yool-Jin Park, Patrick J. Shea,Wang-Hyu Lee, Hyung-Moo Kim, Byung-Taek Oha, Removal of Pb(II) from aqueous solution by a zeolite–nanoscalezero-valent iron composite. Chemical Engineering Journal 217 (2013) 54–60.
 C. Noubactep, On the validity of specific rate constants (kSA) in Fe0/H2O systems’, J. Hazard. Mater. 164 (2009) 835-837.
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