A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement

A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement ( Vol-3,Issue-2,March - April 2018 )

Author: Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan

ijeab doi crossref DOI: 10.22161/ijeab/3.2.1

Keyword: Heavy metal ion, Lab chip sensor, Square-wave anodic stripping voltammetry, in situ measurement.

Abstract: SEM images and FTIR data of the working electrode surface showed that Mn+ ions were adsorbed on chitosan (Chit) and crosslinked chitosan-carbon nanotube (Chit-CNT) films. XPS revealed that chelation of Mn+ ions with the –NH2/–OH groups from chitosan, –COOH group from carbon nanotubes, and aqua ligands represents a possible structure of the active Mn+ species in the Chit-based film. The electrochemical behaviors of the Chit-based film modified screen-printed carbon electrode (SPCE) were characterized for individual and simultaneous detection of Cu2+, Pb2+, Hg2+, Zn2+, Cd2+, and As3+ ions. For individual detection, the concentration range was 0.50–3.00 ppm with a detection limit of 0.4 ppm for Cu2+; 1.0–4.0 ppm with a detection limit of 0.5 ppm for Pb2+; 1.0–5.0 ppm with a detection limit of 0.8 ppm for Hg2+. For simultaneous detection, the lab chip sensor was successfully used to determine the concentrations of Pb2+, Cu2+, Hg2+, and As3+ ions simultaneously.

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Cite this Article:

MLA

Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan et al."A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement". International Journal of Environment Agriculture and Biotechnology(ISSN: 2456-1878),vol 3, no. 2, 2018, pp.308-320 AI Publications doi:10.22161/ijeab/3.2.1

APA

Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan, P.(2018).A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement. International Journal of Environment Agriculture and Biotechnology(ISSN: 2456-1878).3(2), 308-320.10.22161/ijeab/3.2.1

Chicago

Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan, P.(2018).A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement. International Journal of Environment Agriculture and Biotechnology(ISSN: 2456-1878).3(2), pp.308-320.

Harvard

Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan. 2018."A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement". International Journal of Environment Agriculture and Biotechnology(ISSN: 2456-1878).3(2):308-320.Doi:10.22161/ijeab/3.2.1

IEEE

Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan."A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement", International Journal of Environment Agriculture and Biotechnology,vol.3,no. 2, pp.308-320,2018.

Bibtex

@article { kuo-huiwu2018a,
title={A screen-printed carbon electrode modified with a chitosan-based film for in situ heavy metal ions measurement},
author={Kuo-Hui Wu, Je-Chuang Wang, Shin-Yi Yu, Bing-De Yan , R},
journal={International Journal of Environment Agriculture and Biotechnology},
volume={3},
year= {2018} ,
}